PREPARATION OF MACRO-SCALE SPINDLE POLYSTYRENE PARTICLES BY SUSPENSION POLYMERIZATION AND THEIR FORMATION MECHANISM

Preparation of cassava starch grafted with polystyrene by suspension polymerization.

Cassava starch grafted with polystyrene (PS-g-starch) copolymer was synthesized via free-radical polymerization of styrene by using suspension polymerization technique. Potassium persulfate (PPS) was used as an initiator and water was used as a medium. The graft copolymer was characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermal gravimetric analysi...

Preparation and Properties of Branched Polystyrene through Radical Suspension Polymerization

Radical solvent-free suspension polymerization of styrene with 3-mercapto hexyl-methacrylate (MHM) as the branching monomer has been carried out using 2,2′-azobisisobutyronitrile (AIBN) as the initiator to prepare branched polymer beads of high purity. The molecular weight and branching structure of the polymers have been characterized by triple detection size exclusion chromatography (TD-SEC),...

Synthesis of Silica/Polystyrene Nanocomposite Particles by Miniemulsion Polymerization

Miniemulsion polymerization is one of heterogeneous polymerization method that can be effectively used to synthesis of various novel organic-inorganic nanocomposite particles. This method can provide opportunity of good incorporation between the polymer and inorganic phases in the formed submicrometer-sized particles. In this article, we report preparation polystyrene/silica nanocomposite p...

synthesis of silica/polystyrene nanocomposite particles by miniemulsion polymerization

Preparation of polystyrene/polyaniline composite particles and their electrorheology

Monodisperse polystyrene (PS) seed latex was initially prepared by a dispersion polymerization, and then polyaniline (PANI)-coated PS composite particles were synthesized by diffusion and polymerization of aniline at the interface. Characteristics of the obtained PS/PANI composite particles such as morphology and thermal property were examined using SEM and TGA, respectively. In addition, we em...